Studies of the Reactivity of TiO2 (110) and Vanadia Supported on TiO2 (110) Surfaces

adsorbed adsorption adsorption at room annealing benzene Binding Energy butadiene Catal cations CH3OH Chem CO₂ core-level cyclohexanone D2CO DCOOD decomposition decomposition on TiO decomposition product deg 90 deg deg Straddled deposited desorbed desorption Diebold dissociative electron beam electron irradiation ethylene five-fold coordinated flange formaldehyde formate formic acid H2CO Hiroshi Onishi irradiated by electron Kalrez lattice LEED m-xylene M. A. Barteau methanol methoxide ML vanadia molecular molecules monolayer multilayer N/A N/A N/A observed oxygen oxygen treatment oxygen vacancies photoelectron Phys port preparation chamber probe tube propene propylene QMS Signal Arb reaction reactivity reduced V2O5/TiO2 room temperature sealing device sealing mechanism shown in figure single crystal species spectra from DCOOD spectroscopy chamber sputtering stoichiometric surface studied substrate Surf surface at room surface bombarded surface with oxidation surfaces irradiated Teflon Ti³ TiO2 surface titanium cations toluene torr TPRS spectra V2O5/TiO2 surface vanadia vanadia coverage view picture water cell